Criteria for Establishing Accurate Vapor Pressure Curves
نویسنده
چکیده
We use standard thermodynamic relationships to demonstrate the accuracy of new vapor pressure measurements by using them in the calculation ofliquid-phase heat capacities and comparing the results with recently published experimental values. Results for the new alternative refrigerants Rl34a and R 123 are used as examples.
منابع مشابه
Pressure Dependence of Liquid Vapor Pressure: An Improved Gibbs Prediction
A new model for the vapor phase of a pressurized liquid called "the cluster model: which is originally introduced in this work, along with an accurate equation of state for the liquid phase called the LIR, is used to derive an accurate equation for the vapor pressure of liquid as a function of external pressure. The chemical Potential of both phase have been found to be in good agreement wi...
متن کاملAn accurate General Method to Correlate Saturated Vapor Pressure of Pure Substances
In this study, a generalized equation is presented to calculate vapor pressure of pure substances as a function of reduced temperature, critical pressure, and acentric factor. With the presented model, vapor pressures have been calculated and evaluated with NIST data bank for 70 pure substances for about 14000 data points, and the overall average absolute percentage deviation has been only 0.78...
متن کاملA More Accurate Prediction of Liquid Evaporation Flux
In this work, a more accurate prediction of liquid evaporation flux has been achieved. The statistical rate theory approach, which is recently introduced by Ward and Fang and exact estimation of vapor pressure in the layer adjacent to the liquid–vapor interface have been used for prediction of this flux. Firstly, the existence of an equilibrium layer adjacent to the liquid-vapor interface ...
متن کاملAn Efficient Method for Correlation of Vapor Pressure of Gaseous Compounds Containing C-H-O
Prediction of available vapor pressure data in the case of compounds containing C-H-O led to derivations and recommendations of standard equations for this property. The accuracy of vapor pressure estimations is essential to use as a basis to calculate acentric factor, thermal and equilibrium properties. In this study, according to the previous work, an accurate equation to estimate vapor press...
متن کاملEmpirical Correlations and an Artificial Neural Network Approach to Estimate Saturated Vapor Pressure of Refrigerants
The examination of available vapor pressure data in the case of the methane, ethane, propane and butane halogenated refrigerants, allowed recommendations of standard equations for this property. In this study, three new models include a general correlation; a substance-dependent correlation and an artificial neural network (ANN) approach have been developed to estimate the saturated vapor press...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2014